淡江大學機構典藏:Item 987654321/99715
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    题名: End Group Modification of Polynorbornenes
    作者: Lin, Ting-Wei;Chou, Chih-Ming;Lin, Nai-Ti;Lin, Cheng-Lan;Luh, Tien-Yau
    贡献者: 淡江大學化學工程與材料工程學系
    关键词: end‐group modification;ladderphanes;palladium catalysts;polynorbornene;ring‐opening metathesis polymerization
    日期: 2014-12-01
    上传时间: 2014-12-11 13:08:11 (UTC+8)
    出版者: Weinheim: Wiley - V C H Verlag GmbH & Co. KGaA
    摘要: Polynorbornenes with allylic acetoxy terminus are obtained by ring-opening metathesis polymerization of the norbornene derivatives followed by quenching with 1,4-diacetoxy-2Z-butene. Treatment of these polymers with a range of nucleophiles in the presence of a Pd-catalyst gives the corresponding polynorbornenes bearing different end groups. The same protocol is used to modify the end groups of polymeric ladderphanes. Incorporation of an end-group-modified polynorbornene on indium tin oxide (ITO) surface perturbs the electrochemical properties of the ITO electrode.
    關聯: Macromolecular Chemistry and Physics 215(23), pp.2357−2364
    DOI: 10.1002/macp.201400284
    显示于类别:[化學工程與材料工程學系暨研究所] 期刊論文

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