淡江大學機構典藏:Item 987654321/98400
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    题名: TiO2 nanoparticles synthesized in an aprotic solvent and applied to prepare high-refractive-index TiO2-polyimide hybrid thin films
    作者: Chang, Chao-Ching;Hong, Shih-Ya;Cheng, Liao-Ping;Yu, Yang-Yen
    贡献者: 淡江大學化學工程與材料工程學系
    淡江大學能源與光電材料研究中心
    关键词: TiO2 nanoparticle;Aprotic solvent;Polyimide;Sol–gel;High refractive index;Optical thin film
    日期: 2014-07
    上传时间: 2014-07-29 16:18:21 (UTC+8)
    出版者: New York: Springer New York LLC
    摘要: In this study, very small (2–5 nm) TiO2 nanoparticles were synthesized in an aprotic solvent, N,N-dimethylacetamide, via hydrolysis and condensation of titanium alkoxide at room temperature. The synthesized TiO2 sol showed 30 days of storage stability and could be used to prepare high-refractive-index TiO2-polyimide hybrid thin films by an ex-situ method that involved a spin coating and multistep baking process. The field emission scanning electron microscope image showed a flat and uniform morphology of the hybrid thin film. TiO2 domains were in the nanometer range, thus avoiding light scattering. The refractive index at 633 nm of the hybrid thin film reached 2.05, which suggested potential applications of the film to anti-reflective coatings and optical waveguides.
    關聯: Journal of Sol-Gel Science and Technology 71(1), pp.129-135
    DOI: 10.1007/s10971-014-3335-3
    显示于类别:[化學工程與材料工程學系暨研究所] 期刊論文

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