Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes

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题名:	Synthesis, characterization, and reactivity of dinitrosyl iron complexes stabilized by N-heterocyclic carbenes
作者:	Hess, Jennifer L.;Hsieh, Chung-Hung;Darensbourg, Marcetta Y.
贡献者:	淡江大學化學學系
日期:	2011-03
上传时间:	2014-03-28
摘要:	Dinitrosyl iron complexes (DNICs) with S, N, or O coordination function as nitric oxide transfer agents in biol. systems.1,2 However, the few model complexes contg. N-donor ligands, specifically modeling histidine coordination, are extremely air sensitive and difficult to isolate; studies of their reactivity are sparce.3 We report a series of complexes utilizing N-heterocyclic carbenes (NHCs) as mimics of imidazole and histidine ligands. The {Fe(NO)2}10 EPR-silent complexes Fe(NO)2(CO)(IMe), Fe(NO)2(CO)(Ii-Pr), Fe(NO)2
關聯:	241st ACS National Meeting & Exposition, INOR-39
显示于类别:	[化學學系暨研究所] 會議論文

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