Paramagnetic transition metal ions in N2S2 coordination

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Title:	Paramagnetic transition metal ions in N2S2 coordination
Authors:	Pinder, Tiffany A.;Hsieh, Chung-Hung;Lunsford, Allen M.;Darensbourg, Marcetta Y.
Contributors:	淡江大學化學學系
Date:	2012-08
Issue Date:	2014-03-28
Abstract:	Highly versatile tetradentate N2S2 ligands bind to numerous transition metals and, as the Cys-X-Cys motif in proteins, play important roles in metalloenzymes such as Acetyl CoA Synthase and Nitrile Hydratase. We have contributed to extensive studies of M(N2S2) using various metals such as nickel, palladium, and iron with di- and tetraanionic N2S2 donor ligands, and are currently examg. such sites with paramagnetic ions such as [V≡O]2+ and Mn2+. With its d1 electronic configuration, [V≡O]2...
Relation:	244th ACS National Meeting & Exposition, INOR-572
Appears in Collections:	[Graduate Institute & Department of Chemistry] Proceeding

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