Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase

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Title:	Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase
Authors:	Hsieh, Chung-Hung;Erdem, Ozlen;Harman, Scott;Singleton, Michael;Reijerse, Edward;Lubitz, Wolfgang;Popescu, Codrina;Reibenspies, Jospeh;Brothers, Scott;Hall, Michael;et a
Contributors:	淡江大學化學學系
Date:	2013-04
Issue Date:	2014-03-28
Abstract:	The compds. of this study served as structural and functional biomimetics of the [FeFe]-Hydrogenase active site and have demonstrated a redox level-dependent structural rearrangement that is unique in dinuclear organometallic chem. The distinctive "rotated", as contrasted to sym. butterfly, structure is the epicenter of the natural, base metal, hydrogen-producing catalysts. The installation of bridgehead bulk in the -SCH2CR2CH2S- dithiolate (R = Me, Et) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that in the boat c...
Relation:	245th ACS National Meeting & Exposition, INOR-285
Appears in Collections:	[Graduate Institute & Department of Chemistry] Proceeding

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