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    題名: Structural and spectroscopic features of mixed valent FeIIFeI complexes and factors related to the rotated configuration of diiron hydrogenase
    作者: Hsieh, Chung-Hung;Erdem, Ozlen;Harman, Scott;Singleton, Michael;Reijerse, Edward;Lubitz, Wolfgang;Popescu, Codrina;Reibenspies, Jospeh;Brothers, Scott;Hall, Michael;et a
    貢獻者: 淡江大學化學學系
    日期: 2013-04
    上傳時間: 2014-03-28
    摘要: The compds. of this study served as structural and functional biomimetics of the [FeFe]-Hydrogenase active site and have demonstrated a redox level-dependent structural rearrangement that is unique in dinuclear organometallic chem. The distinctive "rotated", as contrasted to sym. butterfly, structure is the epicenter of the natural, base metal, hydrogen-producing catalysts. The installation of bridgehead bulk in the -SCH2CR2CH2S- dithiolate (R = Me, Et) model complexes produces 6-membered FeS2C3 cyclohexane-type rings that in the boat c...
    關聯: 245th ACS National Meeting & Exposition, INOR-285
    顯示於類別:[化學學系暨研究所] 會議論文

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