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    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97597

    題名: N2S2-nickel and iron nitrosyls as metallo ligands in synthetic analogs of the [FeFe]-H2ase enzyme active site
    作者: Darensbourg, Marcetta Y.;Hsieh, Chung-Hung;Ghosh, Pokhraj
    貢獻者: 淡江大學化學學系
    日期: 2013-04
    上傳時間: 2014-03-28
    摘要: The unique diiron catalytic unit that exists in the active site of the [FeFe]-H2ase has obvious design features that have been exploited in the development of hydrogen processing catalysts utilizing earth abundant metals, nickel and iron. In particular, the pendant base feature within the bridging dithiolate has been adapted within a nickel-diphosphinocyclohexane-like ring providing a remarkable catalyst for H2 prodn.(Helm, Dubois, et al., Science, 2011 , 863-866) We will describe modifications of the (μ-S(CH2)3S)[Fe(CO)3]2 p..
    關聯: 245th ACS National Meeting & Exposition, INOR-636
    顯示於類別:[化學學系暨研究所] 會議論文





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