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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97595


    Title: Iron-nitrosyl paradigm for base metal proton reduction electrocatalysis
    Authors: Darensbourg, Marcetta Y.;Hsieh, Chung-hung;Erdem, Ozlen;Ding, Shengda;Crouthers, Danielle;Lubitz, Wolfgang;Popescu, Codrina;Reibenspies, Joseph;Hall, Michael B.
    Contributors: 淡江大學化學學系
    Date: 2013-11
    Issue Date: 2014-03-28
    Abstract: Base metal, mol. catalysts for the fundamental process of conversion of protons and electrons to dihydrogen remain a substantial synthetic goal related to a sustainable energy future. A novel approach has produced a diiron complex with bridging thiolates in the butterfly shape of the 2Fe2S core of the [FeFe]-hydrogenase active site, but with NO rather than CO or CN- ligands, that is demonstrated to maintain structural integrity in two redox levels. Various spectroscopies corroborate the roles of the iron centers in electrocatalytic proton redn. The binuclear [(NO)Fe(N2
    Relation: 69th Southwest Regional Meeting of the American Chemical Society, SWRM-576
    Appears in Collections:[化學學系暨研究所] 會議論文

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