Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds

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题名:	Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds
作者:	Ghosh, Pokhraj;Hsieh, Chung-Hung;Darensbourg, Marcetta Y.
贡献者:	淡江大學化學學系
日期:	2013-04
上传时间:	2014-03-28
摘要:	The reversible redn. of protons to form hydrogen gas is known to be catalyzed by the active-site of the diiron hydrogenase, [FeFe]-H2ase. The N2S2Ni (square planar), N2S2-Co(NO) and -Fe(NO) (square pyramidal) compds. are particularly interesting as the cis-dithiolates are noted for their nucleophilicity toward a diverse variety of electrophiles and their ability to lower the redn. potentials on coordination with M(CO)x. In this project a series of [FeFe]-H2ase active site model compds. are shown to form stable addu...
關聯:	245th ACS National Meeting & Exposition, INOR-281
显示于类别:	[化學學系暨研究所] 會議論文

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