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    題名: Electronic effects of metallodithiolate ligands on [FeFe]-H2ase active site model compounds
    作者: Ghosh, Pokhraj;Hsieh, Chung-Hung;Darensbourg, Marcetta Y.
    貢獻者: 淡江大學化學學系
    日期: 2013-04
    上傳時間: 2014-03-28
    摘要: The reversible redn. of protons to form hydrogen gas is known to be catalyzed by the active-site of the diiron hydrogenase, [FeFe]-H2ase. The N2S2Ni (square planar), N2S2-Co(NO) and -Fe(NO) (square pyramidal) compds. are particularly interesting as the cis-dithiolates are noted for their nucleophilicity toward a diverse variety of electrophiles and their ability to lower the redn. potentials on coordination with M(CO)x. In this project a series of [FeFe]-H2ase active site model compds. are shown to form stable addu...
    關聯: 245th ACS National Meeting & Exposition, INOR-281
    顯示於類別:[化學學系暨研究所] 會議論文

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