Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Ni, Fe, Co) as metallodithiolate ligands

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Title:	Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M=Ni, Fe, Co) as metallodithiolate ligands
Authors:	Chupik, Rachel B.;Hsieh, Chung-Hung;Darensbourg, Marcetta Y.
Contributors:	淡江大學化學學系
Date:	2013-04
Issue Date:	2014-03-28
Abstract:	Reduced {Fe(NO)2} complexes are formed by reaction of Fe(CO)2(NO)2 with Ni(N2S2) (N2S2 = N,N'-Bis(2-mercaptoethyl)-1,4-diazacycloheptane (bme-dach) and N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctane (bme-daco)). A single CO is replaced, yielding [Ni(N2S2)]Fe(NO)2(CO); however, with N2S2 = bme-dach, excess of Fe(NO)2(CO)2 leads to a cluster of core compn. Ni2S4Fe3 with triply bridging thiolate sulfurs. In the...
Relation:	245th ACS National Meeting & Exposition, INOR-291
Appears in Collections:	[Graduate Institute & Department of Chemistry] Proceeding

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