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    Title: Cis-NiN2S2 metallodithiolates as mono- and bidentate S-donors to gold (I)
    Authors: Pinder, Tiffany A.;Montalvo, Steven K.;Lunsford, Allen M.;Hsieh, Chung-Hung;Reibenspies, Joseph H.;Darensbourg, Marcetta Y.
    Contributors: 淡江大學化學學系
    Date: 2013-04
    Issue Date: 2014-03-28
    Abstract: Metal-bound thiolates show S-based reactivity including alkylation, oxygenation, and metalation. We have studied the donating ability of a series of square planar,NiN2S2 complexes by reporter units such as tungsten carbonyls and dinitrosyl iron complexes. In this way nickel cis-dithiolates may be described as metallo ligands, comparable to diphenylphosphinoethane or bipyridine. Herein we describe the products of reaction of [NiN2S2 ]n (n = 0 or 2-) complexes with Ph3PAuCl, with expectation of a thiolate S-donor to...
    Relation: 245th ACS National Meeting & Exposition, INOR-1363
    Appears in Collections:[化學學系暨研究所] 會議論文

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