淡江大學機構典藏:Item 987654321/97591
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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/97591


    Title: Ambidentate thiocyanate ligand in dinitrosyl iron complexes
    Authors: Hsieh, Chung-Hung;Brothers, Scott M.;Hall, Michael B.;Popescu, Codrina V.;Darensbourg, Marcetta Y.
    Contributors: 淡江大學化學學系
    Date: 2013-04
    Issue Date: 2014-03-28
    Abstract: Ambidentate ligands such as thiocyanate (SCN-), cyanate (OCN-) and azide (N3 -) have played important roles in the development of bonding models relating to factors that control linkage isomerism in transition metal complexes. However, examples of DNICs, for which oxidn. states of iron are ambiguous, contg. these ambidentate ligands are rare. Two redox levels are prevalent for DNICs, represented in the Enemark-Feltham (E-F) notation as {Fe(NO)2}9 and {Fe(NO)2}10 for oxidized and reduced levels resp., eac...
    Relation: 245th ACS National Meeting & Exposition, INOR-96
    Appears in Collections:[Graduate Institute & Department of Chemistry] Proceeding

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