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    題名: Ambidentate thiocyanate ligand in dinitrosyl iron complexes
    作者: Hsieh, Chung-Hung;Brothers, Scott M.;Hall, Michael B.;Popescu, Codrina V.;Darensbourg, Marcetta Y.
    貢獻者: 淡江大學化學學系
    日期: 2013-04
    上傳時間: 2014-03-28
    摘要: Ambidentate ligands such as thiocyanate (SCN-), cyanate (OCN-) and azide (N3 -) have played important roles in the development of bonding models relating to factors that control linkage isomerism in transition metal complexes. However, examples of DNICs, for which oxidn. states of iron are ambiguous, contg. these ambidentate ligands are rare. Two redox levels are prevalent for DNICs, represented in the Enemark-Feltham (E-F) notation as {Fe(NO)2}9 and {Fe(NO)2}10 for oxidized and reduced levels resp., eac...
    關聯: 245th ACS National Meeting & Exposition, INOR-96
    顯示於類別:[化學學系暨研究所] 會議論文

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