Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs)

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题名:	Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs)
作者:	Drummond, Michael J.;Pulukkody, Randara;Kyran, Samuel J.;Hsieh, Chung Hung;Darensbourg, Donald J.;Darensbourg, Marcetta Y.
贡献者:	淡江大學化學學系
日期:	2014-03
上传时间:	2014-03-28
摘要:	Dinitrosyliron complexes (DNICs) are biol. relevant mols. involved in nitric oxide (NO) transport and storage in biol. systems. Biol. DNICs are known to be products of iron-sulfur cluster degrdn. by excess NO, or derived from the chelatable iron pool (CIP) in cells; synthetic DNIC analogs have potential as NO storage and release agents with therapeutic benefit. The dinitrosyl iron unit is known to exist in two redox levels; its oxidized and reduced forms, {Fe(NO)2}9 and {Fe(NO)2}10 resp. (Enemark-Feltham notation) with redox potentials dependent o...
關聯:	247th ACS National Meeting & Exposition, CHED-774
显示于类别:	[化學學系暨研究所] 會議論文

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