Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs)

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Title:	Further mechanistic studies of carbon monoxide induced reductive elimination of disulfide in N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complexes (DNICs)
Authors:	Drummond, Michael J.;Pulukkody, Randara;Kyran, Samuel J.;Hsieh, Chung Hung;Darensbourg, Donald J.;Darensbourg, Marcetta Y.
Contributors:	淡江大學化學學系
Date:	2014-03
Issue Date:	2014-03-28
Abstract:	Dinitrosyliron complexes (DNICs) are biol. relevant mols. involved in nitric oxide (NO) transport and storage in biol. systems. Biol. DNICs are known to be products of iron-sulfur cluster degrdn. by excess NO, or derived from the chelatable iron pool (CIP) in cells; synthetic DNIC analogs have potential as NO storage and release agents with therapeutic benefit. The dinitrosyl iron unit is known to exist in two redox levels; its oxidized and reduced forms, {Fe(NO)2}9 and {Fe(NO)2}10 resp. (Enemark-Feltham notation) with redox potentials dependent o...
Relation:	247th ACS National Meeting & Exposition, CHED-774
Appears in Collections:	[Graduate Institute & Department of Chemistry] Proceeding

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