English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 49378/84106 (59%)
造訪人次 : 7378076      線上人數 : 67
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/97588

    題名: S-S Bond-activation of diorganyl disulfide by anionic [Mn(CO)5]-: crystal structures of [MnII(-SC5H4NO-)3]- and [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3]- (R = C6H4NHCOPh)
    作者: Liaw, Wen-Feng;Hsieh, Chung-Hung;Peng, Shie-Ming;Lee, Gene-Hsiang
    貢獻者: 淡江大學化學學系
    關鍵詞: Manganese(II)–thiolate;S-S Bond-activation;Heterotrinuclear Mn-Co-Mn-thiolate
    日期: 2002-04
    上傳時間: 2014-03-27 16:10:07 (UTC+8)
    出版者: Amsterdam: Elsevier BV
    摘要: The S-S bond-activation of diorganyl disulfide by the anionic metal carbonyl fragment [Mn(CO)5]− gives rise to an extensive chemistry. Oxidative decarbonylation addition of 2,2′-dithiobis(pyridine-N-oxide) to [Mn(CO)5]−, followed by chelation and metal-center oxidation, led to the formation of [MnII(-SC5H4NO-)3]− (1). The effective magnetic moment in solid state by SQUID magnetometer was 5.88 μB for complex 1, which is consistent with the MnII having a high-spin d5 electronic configuration in an octahedral ligand field. The average Mn(II)-S, S-C and N-O bond lengths of 2.581(1), 1.692(4) and 1.326(4) Å, respectively, indicate that the negative charge of the bidentate 1-oxo-2-thiopyridinato [SC5H4NO]− ligand in complex 1 is mainly localized on the oxygen atom. The results are consistent with thiolate-donor [-SC5H4NO]− stabilization of the lower oxidation state of manganese (Mn(I)), while the O,S-chelating [-SC5H4NO-]− ligand enhances the stability of manganese in the higher oxidation state (Mn(II)). Activation of S-S bond as well as O-H bond of 2,2′-dithiosalicylic acid by [Mn(CO)5]− yielded [(CO)3Mn(μ-SC6H4-C(O)-O-)2Mn(CO)3]2− (4). Oxidative addition of bis(o-benzamidophenyl) disulfide to [Mn(CO)5]− resulted in the formation of cis-[Mn(CO)4(SR)2]− (R=C6H4NHCOPh) which was employed as a chelating metallo ligand to synthesize heterotrinuclear [(CO)3Mn(μ-SR)3Co(μ-SR)3Mn(CO)3]− (8) possessing a homoleptic hexathiolatocobalt(III) core.
    關聯: Inorganica Chimica Acta 332(1), pp.153-159
    DOI: 10.1016/S0020-1693(02)00733-8
    顯示於類別:[化學學系暨研究所] 期刊論文


    檔案 描述 大小格式瀏覽次數



    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋