数据加载中.....
|
jsp.display-item.identifier=請使用永久網址來引用或連結此文件:
https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/97584
|
| 题名: | Photochemistry of the Dinitrosyl Iron Complex [S5Fe(NO)2]- Leading to Reversible Formation of [S5Fe(μ-S)2FeS5]2-: Spectroscopic Characterization of Species Relevant to the Nitric Oxide Modification and Repair of [2Fe−2S] Ferredoxins |
| 作者: | Tsai, Ming-Li;Chen, Chiao-Chun;Hsu, I-Jui;Ke, Shyue-Chu;Hsieh, Chung-Hung;Chiang, Kuo-An;Lee, Gene-Hsiang;Wang, Yu;Chen, Jin-Ming;Lee, Jyh-Fu;Liaw, Wen-Feng |
| 贡献者: | 淡江大學化學學系 |
| 日期: | 2004-08 |
| 上传时间: | 2014-03-27 14:57:04 (UTC+8) |
| 出版者: | Washington, DC: American Chemical Society |
| 摘要: | The reaction of [PPN][Fe(CO)3(NO)] and S8 in a 1:1 molar ratio in THF proceeded to give the dinitrosyl iron complex [PPN][S5Fe(NO)2] (1) and the known [PPN]2[S5Fe(μ-S)2FeS5] (2). EPR signals of g values gz = 2.0148, gx = 2.0270, and gy = 2.0485 at 77 K confirmed the existence of the unpaired electron in compound 1. The temperature-dependent magnetic moment of complex 1 indicates that the ground state is one unpaired electron with (St, SL) = (1/2, 1) at very low temperature (St is the total spin quantum number of the system; SL is the sum of the spin quantum numbers of two NO ligands). The O K-edge absorptions of complex 1 and [(NO)Fe(S2CNEt2)2] at 532.1 and 532.5 eV are assigned to the transition of 1s → π*(NO) and 1s → π*(NO+), respectively. For the electronic structure of the {Fe(NO)2} core, DFT calculations, magnetic susceptibility measurement, EPR, and Fe K-/L-edge XAS spectroscopy of complex 1 lead to a description of {Fe1+(•NO)2}9. [2Fe−2S] cluster 2 treated with nitric oxide in THF shows that cluster 2 is transformed into the dinitrosyl iron complex 1 identified by IR, UV−vis, and X-ray diffraction analysis. The reaction may be reversed by the photolysis of the THF solution of 1 in the presence of the NO-accepting reagent [(C4H8O)Fe(S,S-C6H4)2]- to reform 2. This result demonstrates a successful biomimetic reaction cycle of the degradation and reassembly of [2Fe−2S] cluster [S5Fe(μ-S)2FeS5]2- relevant to the repair of nitric oxide-modified [2Fe−2S] ferredoxin by cysteine desulfurase and l-cysteine in vitro. |
| 關聯: | Inorganic Chemistry 43(16), pp.5159-5167 |
| DOI: | 10.1021/ic0494915 |
| 显示于类别: | [化學學系暨研究所] 期刊論文
|
文件中的档案:
| 档案 |
描述 |
大小 | 格式 | 浏览次数 |
|---|
| index.html | | 0Kb | HTML | 81 | 检视/开启 |
|
在機構典藏中所有的数据项都受到原著作权保护.
|
