A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion

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题名:	A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion
作者:	Hsieh, Chung-Hung;Pulukkody, Randara;Darensbourg, Marcetta Y.
贡献者:	淡江大學化學學系
日期:	2013-08-16
上传时间:	2014-03-26 10:43:53 (UTC+8)
出版者:	Cambridge: R S C Publications
摘要:	An N-alkyl imidazole bearing a neutral {Fe(NO)2}10 dinitrosyliron complex (DNIC) when treated with sodium t-butoxide undergoes base-promoted conversion to the N-heterocyclic carbene (NHC)–DNIC, while maintaining the Fe(NO)2 unit intact. Subsequent alkylation led to the isolation of the NHC–DNIC product; further nitrosylation led to trinitrosyl (NHC)Fe(NO)3+. Both were isolated and structurally characterized.
關聯:	Chemical Communications 49(81), pp.9326-9328
DOI:	10.1039/C3CC45091K
显示于类别:	[化學學系暨研究所] 期刊論文

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