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    Title: A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion
    Authors: Hsieh, Chung-Hung;Pulukkody, Randara;Darensbourg, Marcetta Y.
    Contributors: 淡江大學化學學系
    Date: 2013-08
    Issue Date: 2014-03-26 10:43:53 (UTC+8)
    Publisher: Cambridge: R S C Publications
    Abstract: An N-alkyl imidazole bearing a neutral {Fe(NO)2}10 dinitrosyliron complex (DNIC) when treated with sodium t-butoxide undergoes base-promoted conversion to the N-heterocyclic carbene (NHC)–DNIC, while maintaining the Fe(NO)2 unit intact. Subsequent alkylation led to the isolation of the NHC–DNIC product; further nitrosylation led to trinitrosyl (NHC)Fe(NO)3+. Both were isolated and structurally characterized.
    Relation: Chemical Communications 49(81), pp.9326-9328
    DOI: 10.1039/C3CC45091K
    Appears in Collections:[化學學系暨研究所] 期刊論文

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