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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/96064


    Title: Diffusiophoresis of Polyelectrolytes in Nanodevices: Importance of Boundary
    Authors: Hsu, Jyh-Ping;Liu, Kuan-Liang;Tseng, Shiojenn
    Contributors: 淡江大學數學學系
    Date: 2013-04
    Issue Date: 2014-02-17 11:35:19 (UTC+8)
    Publisher: Washington: The Journal of Physical Chemistry
    Abstract: Considering the potential applications of diffusiophoresis conducted in nanodevices, a thorough theoretical analysis is performed for the first time on the diffusiophoresis of a polyelectrolyte (PE) in the presence of two representative types of boundaries: the direction of diffusiophoresis is either normal (type I) or parallel (type II) to a boundary, using two large parallel disks and a cylindrical pore as an example, respectively. It is interesting to observe that due to the effects of double-layer polarization, counterion condensation, polarization of condensed counterions, and diffusion of co-ions across a PE, its diffusiophoretic behavior can be influenced both quantitatively (magnitude of mobility) and qualitatively (direction of diffusiophoresis) by a boundary. In general, type I (II) boundary raises the diffusiophoretic mobility of a PE toward the high (low) salt concentration side. The results gathered provide necessary information for applications in, for example, designing catalytic swimmers and nanopore-based biosensor devices.
    Relation: The Journal of Physical Chemistry C 117(18), pp.9469–9476
    DOI: 10.1021/jp312702r
    Appears in Collections:[數學學系暨研究所] 期刊論文

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