幾丁聚醣選擇性接枝聚異丙基丙烯醯胺以合成出共聚合體水膠

淡江大學機構典藏 > 工學院 > 化學工程與材料工程學系暨研究所 > 會議論文 > Item 987654321/94985

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题名:	幾丁聚醣選擇性接枝聚異丙基丙烯醯胺以合成出共聚合體水膠
其它题名:	Synthesis of Chitosan Copolymers Selectively Grafted withPoly(N-Isopropylacrylamide)
作者:	董崇民;方裕榮;陳怡雯
贡献者:	淡江大學化學工程學系
关键词:	Chitosan;Poly(N-isopropylacrylamide);Glycidyl methacrylate;Graft copolymer
日期:	2006-05
上传时间:	2014-02-09 00:52:26 (UTC+8)
摘要:	In this study, poly(N-isopropylacrylamide)(PNIPAAm) was selectively grafted onto chitosan to form a copolymer hydrogel. To accomplish this goal, the amino group of chitosan (CS) was protected by reaction with phthalic anhydride, which also rendered the modified chitosan soluble in organic solvent. The N-phthaloyl chitosan was then reacted with glycidyl methacrylate (GMA) selectively through hydroxyl groups in glucopyranose rings, to provide vinyl functional groups for further graft copolymerization with NIPAAm monomer by free radical polymerization. The phthaloyl groups were removed under the reaction with hydrazine solution. Structures of the intermediates and final CS-g-PNIPAAm copolymer products were analyzed by Fourier transform infrared spectrometer and nuclear magnetic resonance. Several properties such as swelling behavior, thermal properties and cell compatibility of the formed chitosan-g-PNIPAAm copolymers were evaluated.
關聯:	2006台灣幾丁質幾丁聚醣研討會論文集，4頁
显示于类别:	[化學工程與材料工程學系暨研究所] 會議論文

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