本研究係利用電漿活化接枝技術,將不同單體(壓克力酸:AA及甲基丙烯酸環氧丙酯:GMA)接枝於聚二氟乙烯(PVDF)上,利用酸鹼滴定法及核磁共振儀分析來檢測接枝量。並將不同單體接枝量之改質PVDF利用摻合(Blending)技術,使其與聚硫化苯(PPS)充分混煉。利用電子顯微鏡(SEM)觀察聚摻合後之材料界面間相容性與相形態的變化,並以DSC的檢測摻合物之物理性質隨相容性的變化關係。 This research covers the grafting of different monomers, Acrylic acid(AA) and Glycidyl methacrylate (GMA), to polyvinylidene fluoride(PVDF) by using technology of plasma reaction. The modified PVDF isblended with PPS by in-situ reactive process. The phase morphology andthe thermal behavior of blends are studied with SEM and DSC. Theinterfacial compatibility and physical property is observed anddiscussed.
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第二十四屆高分子研討會論文專輯2001=Proceediings of the 24th ROC Polymer Symposium 2001