聚偏二氟乙烯接枝聚甲基丙烯酸甲酯之原子轉移自由基合成與其自組裝行為的探討 Study of Atom Transfer Free Radical Synthesis and Self-Assembly Behavior of PVDF-g-PMMA

淡江大學機構典藏 > 工學院 > 化學工程與材料工程學系暨研究所 > 會議論文 > Item 987654321/94919

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/94919

题名:	聚偏二氟乙烯接枝聚甲基丙烯酸甲酯之原子轉移自由基合成與其自組裝行為的探討 Study of Atom Transfer Free Radical Synthesis and Self-Assembly Behavior of PVDF-g-PMMA
作者:	李威儒;林俊良;林達鎔
贡献者:	淡江大學化學工程與材料工程學系
关键词:	原子轉移自由基聚合法;接枝共聚物;自組裝行為;Atom transfer radical polymerization;Graft-copolymer;Nanopore;Self-assembly behavior
日期:	2007-01
上传时间:	2014-02-09 00:42:17 (UTC+8)
摘要:	本實驗以原子轉移自由基聚合法(Atom transfer radical polymerization, ATRP)合成聚偏二氟乙烯高分子與聚甲基丙烯酸甲酯之接枝共聚物。接枝共聚物的合成以傅利葉紅外線光譜儀(FTIR)與核磁共振光譜儀(NMR)鑑別接枝共聚物之化學結構。將接枝共聚物摻混聚甲基丙烯酸甲酯製成多孔性薄膜，由於接枝共聚物的自組裝行為(Self-assembly)，使得接枝共聚物與PMMA複合膜達到100nm以下的相分離層級，由FESEM觀察得知多孔性薄膜的截面孔洞約20至100nm之間且分佈均勻。 The present research utilized PVDF and MMA to synthesize graft copolymer by the method of atom transfer radical polymerization. The chemical structure of graft copolymers was confirmed by FT-IR and NMR. The graft copolymer was blended with PMMA to make solution dopes for the preparation of dense films with self-assembly nanostructure by dry method. The dense films were treated by extraction to make porous membranes. The morphology of the prepared composite membranes were investigated by SEM. The size of connected pores observed in membrane cross-section fell in the range of about 20-100 nm. The result of homogeneous, uniform morphology proves that the system is greatly modified by the presence of the graft copolymer which is characterized by its self assembly behavior.
關聯:	2007高分子聯合會議論文集=Proceedings of 2007 Annual Polymer Conference，5頁
显示于类别:	[化學工程與材料工程學系暨研究所] 會議論文

文件中的档案:

档案	描述	大小	格式	浏览次数
聚偏二氟乙烯接枝聚甲基丙烯酸甲酯之原子轉移自由基合成與其自組裝行為的探討_中文摘要.docx	摘要	18Kb	Microsoft Word	110	检视/开启
聚偏二氟乙烯接枝聚甲基丙烯酸甲酯之原子轉移自由基合成與其自組裝行為的探討_英文摘要.docx	摘要	18Kb	Microsoft Word	94	检视/开启

在機構典藏中所有的数据项都受到原著作权保护.

TAIR相关文章

数据加载中.....