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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/94911


    Title: PPS/PA12摻合系統之相界面相容性反應研究與分析
    Authors: 林達鎔;黃清俊
    Contributors: 淡江大學化學工程學系
    Keywords: 聚亞苯基硫醚;聚醯胺12;相容化;摻合物;順丁烯二酐;苯乙烯;嵌段共聚物;原位反應;Poly;Polyamide 12;Compatibilization;Blend;Maleic Anhydride;Styrene;Block Copolymer;In Situ Reaction
    Date: 1997-06
    Issue Date: 2014-02-09 00:41:02 (UTC+8)
    Abstract: 本論文主要是研究在PPS/PA12摻合系統中, 加入反應性單體 MAH 及Styrene, 使得這兩種單體能藉由原位(In-situ)反應的方式, 在相界面間原位生成(In-situ formation)所需要的相容劑。並藉由熱溶洗出連續相的方法, 收集分散相, 以FTIR做相界面共聚物含量的定量分析。而動態機械分析(DMA)及微觀相型態(SEM)等測試, 則被用來探討相界面共聚物含量對摻合系統所造成的影響。研究結果發現:在PPS/PA12(30/70)摻合系統中, 加入MAH及Styrene單體, 可以大幅提高相界面含量, 而MAH與Styrene的最佳比例為 2:2 phr。動態機械分析顯示, 相界面共聚物含量增加, 會使得PPS與PA12的玻璃轉移溫度更相互靠近。而在微觀相形態的觀察, 則發現加入單體後, 相界面有變化顯示有相容性共聚物的生成。
    The polyblends of PPS and PA12 were studied. It is observed that addition of small molecules with multi- functionality, maleic anhydride (MAH) and styrene, during blending of PPS and PA12 increases the compatibilization between these two polymers. This is due to the fact that MAH and styrene can react with PPS and PA12 to form in- situ, block copolymers PPS-b-PA12 at polymer interface, which is confirmed by FTIR spectrometry. The evidence of improving compatibility due to reactive blending is revealed by analysis of dynamic mechanical behavior and morphology.
    Relation: 第二十屆高分子研討會論文專輯第十二卷第二冊=Proceedings of the 20th ROC Polymer Symposium 1997
    Appears in Collections:[Graduate Institute & Department of Chemical and Materials Engineering] Proceeding

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