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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/94366


    Title: 三氧化鎢氧化矽複合薄膜之製備與其電化學與電致色變性質之研究
    Other Titles: Study on the preparation of tungsten trioxide/silica composite thin films and their electrochemical and electrochromic properties
    Authors: 楊恭祥;Yang, Kung-Shiang
    Contributors: 淡江大學化學工程與材料工程學系碩士班
    林正嵐;Lin, Cheng-Lan
    Keywords: 四乙氧基矽烷;三氧化鎢;氧化矽;電致色變;tungsten trioxide;Silica;composite films;electrochromic
    Date: 2013
    Issue Date: 2014-01-23 14:28:38 (UTC+8)
    Abstract: 本研究以金屬鎢粉和雙氧水為起始物,添加四乙氧基矽烷(Tetraethyl orthosilicate, TEOS, Mw=208.33g/mol)並以無水乙醇為溶劑製備前驅物,利用溶膠/凝膠法搭配旋轉塗佈法,於FTO導電基材上製備三氧化鎢(WO3)薄膜。藉由改變鎢與矽之莫耳比,修飾所得三氧化鎢薄膜之微結構。利用掃描式電子顯微鏡對薄膜進行表面成分,利用FTIR進行化學鍵結分析,利用恆電位/恆電流儀和紫外光/可見光光譜儀同步量測進行定性與定量分析,量測薄膜之電化學行為、著/去色應答時間、著/去色吸收光譜、穿透度調幅以及著色效率。利用電化學阻抗分析估算各介面之阻抗,進而得知鋰離子於三氧化鎢薄膜中的擴散係數。推論氧化矽在系統中可抑制三氧化鎢晶型的生成。W:Si=90:10莫耳比之三氧化鎢/氧化矽複合薄膜擁有較佳穿透度差值(ΔT = 59.49% @ 550 nm),於550 nm波長之著色/去色應答時間為9.0 s/1.9 s;經過階梯電位100次切換後,穩定性最高,ΔA100/ΔA1比值達79.93%,遠高於純三氧化鎢薄膜的40.15%;且該樣品經階梯電位100次切換後,著色效率由30.88cm2/C提升至44.36cm2/C,吸收度差值ΔA保有0.394;由電化學阻抗分析得知其擴散係數為4.90×〖10〗^(-11)cm2/s。
    A sol-gel derived peroxotungstic acid (PTA) sol has been employed for the deposition of tungsten trioxide-silica nanocomposite (WO3-SiOx) thin films and pure tungsten trioxide (WO3) thin films on fluorine doped-tin oxide (FTO) conductive glass by spin coating technique. As changing the molar ratio of W to Si, we can observe different properties. By using scanning electron microscopy (SEM) and X-ray diffraction (XRD), we can know micro-structure and crystalline structure of composite films respectively. In electrochemistry aspect, using Potentiostat/Galvanostat to get response time, stability and quantity, and using electrochemical impedance spectroscopy (EIS) to get the information of the diffusion of lithium. And optical properties observed by UV/Visible, like overall wavelength scanning and transmittance spectrum. Besides, we find the optimum component for the ratio of W to Si.
      The results show that when the molar ratio of W to Ti is 90 to 10 (WSi-10), the film has uniform and transparent surface and the structure reveals amorphous phase. There is the best electrochemical stability and transmittance modulation (△T = 59.49% @ 550 nm) in this condition. At 550nm irradiation, the coloring and bleaching time of the film are 9.0 s and 1.9 s. The stability experiment shown that after switching 100 times of potential steps, the ratio of ΔA100/ΔA1 is 79.93% higher than WO3 thin film. By using ZView software to fit the EIS data, the diffusion coefficient of the film is 4.90×〖10〗^(-11)cm2/s.
    Appears in Collections:[化學工程與材料工程學系暨研究所] 學位論文

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