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    Title: 利用鈀金屬催化進行碳氫鍵活化合成芴酮
    Other Titles: Palladium-catalyzed C-H activation for the synthesis fluorenone
    Authors: 黃俊銘;Huang, Jun-Min
    Contributors: 淡江大學化學學系碩士班
    謝仁傑
    Keywords: 聯苯腈;碳氫鍵活化;芴酮;Suzuki-Miyaura coupling reaction;C-H activation;Fluorenone
    Date: 2013
    Issue Date: 2014-01-23 13:44:59 (UTC+8)
    Abstract: (1)利用Suzuki-Miyaura coupling reaction方式合成聯苯腈起始物(2)利用[Pd]/[Ag]/TFA系統催化聯苯腈類起始物進行碳-氫鍵活化合成芴酮。利用實驗室所得到最佳化反應條件:(1) 0.5 mmol(1當量) 聯苯睛,10 mol% Pd(MeCN)2Cl2、20 mol % AgTFA、1.1當量 H2O、1.5 mL TFA、0.75 mL DMA。
    The biphenyl derivatives were synthesized by Suzuki- Miyaura coupling reaction to obtain the starting materials. A novel procedure employed [Pd]/[Ag]/TFA system catalyzed cascade reactions of nitrile directed remote C-H bond activation that afforded variously polysubstituted fluorenones in moderate to good yields with tolerance of a wide variety of substrates.
    Appears in Collections:[化學學系暨研究所] 學位論文

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