淡江大學機構典藏:Item 987654321/87394
English  |  正體中文  |  简体中文  |  全文笔数/总笔数 : 62819/95882 (66%)
造访人次 : 4006865      在线人数 : 541
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜寻范围 查询小技巧：
  • 您可在西文检索词汇前后加上"双引号"，以获取较精准的检索结果
  • 若欲以作者姓名搜寻，建议至进阶搜寻限定作者字段，可获得较完整数据
    •  进阶搜寻


    jsp.display-item.identifier=請使用永久網址來引用或連結此文件: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/87394


    题名: 利用X光吸收光譜和磁圓偏振二向性研究多鐵異質結構CoFe2O4-PbTiO3的原子與電子結構及磁特性
    其它题名: The atomic, electronic structures and magnetic properties of multiferroic hetero-structures CoFe2O4-PbTiO3 studied by x-ray absorption spectroscopy and magnetic circular dichroism
    作者: 王孝祖;Wang, Hsiao-Tsu
    贡献者: 淡江大學物理學系碩士班
    彭維鋒
    关键词: X光吸收光譜;X光磁圓二向性譜;元素解析之磁滯曲線;多鐵材料;EXAFS;XMCD;ESMH;Multiferroic;CoFe2O4;PbTiO4
    日期: 2012
    上传时间: 2013-04-13 11:02:50 (UTC+8)
    摘要: 本論文利用Co、Fe與Ti K-edge延伸Ｘ光吸收精細結構(Extended X-ray Absorption Fine Structure, EXAFS)及磁圓二向性(X-ray Magnetic Circular Dichrism, XMCD)研究一系列的不同幾何形狀如:0維CoFe2O4嵌入三維PbTiO3以及二維CoFe2O4與PbTiO3交互推疊而成的多鐵異質結構CoFe2O4-PbTiO3的原子與電子及磁性特質。從Fe與Co的 EXAFS分析結論，CoFe2O4並非是完美的反尖晶石結構，Co與Fe皆能共存於四面體與八面體之間。根據X光繞射圖(X-Ray Diffraction, XRD)的實驗數據，推測PbTiO3因不同的幾何形狀造成CoFe2O4受到不同的應力，進而導致CoFe2O4離子重新組合的可能。根據Ti XMCD並未觀察Ti因介面效應而產生磁性。說明樣品之磁性皆源自CoFe2O4之幾何形狀差異。利用 XMCD發現到樣品隨著幾何結構改變時，對於磁性造成的改變與CoFe2O4的離子交換及反相磁域有關。
    Investigation has been made on electronic, atomic structures and magnetic properties of multiferroics composite [CoFe2O4 (CFO) particles embedded in PbTiO3 (PTO) matrix (0-3 type)] and multilayer [CFO-PTO multilayered (2-2 type)] samples by using Extended X-ray Absorption Fine Structure (EXAFS) and X-ray Magnetic Circular Dichroism (XMCD). Co and Fe K-edge indicates the cation distribution of CFO in these (0-3 and 2-2 type) samples were deviated from the perfect inverse spinel structure, suggesting the changes of local atomic structure from inverse spinel to normal spinel due to induced strain effect of adjacent PTO. The Ti reveal no any magnetic moment due to interface effect, measurement by XMCD, which attributes the observed change in magnetic properties are basically coming from the CoFe2O4. The decrease in magnetic moment were also observed in multiferroics composite (0-3 type) and multilayer (2-2 type) samples, in comparison to CFO particles. The significant changes in magnetic moments suggest the antiferromagnetic (AF) alignment of cations due to the cation distribution and Anti-phase domin.
    显示于类别:[物理學系暨研究所] 學位論文

    文件中的档案:

    档案 大小格式浏览次数
    index.html0KbHTML187检视/开启

    在機構典藏中所有的数据项都受到原著作权保护.

    TAIR相关文章

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回馈