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    題名: 顆粒型PVDF薄膜之製備、改質及在生醫技術上的應用(II)
    作者: 張啟林;鄭廖平;林達鎔
    貢獻者: 淡江大學化學工程與材料工程學系
    日期: 2008
    上傳時間: 2013-04-09 11:46:44 (UTC+8)
    摘要: 本研究利用濕式相轉換製備聚偏二氟乙烯(PVDF)與聚甲基丙烯酸甲酯(PMMA)之複合薄膜,溶劑為二甲亞風(DMSO),非溶劑為水與DMSO。藉由不同濃度之沈澱槽(純水、40%DMSO、70%DMSO)製作出不同型態之複合薄膜,並以SEM、拉力試驗機、DSC、XRD來作測試。隨著PMMA的加入,薄膜之SEM有明顯的差異;抗張強度漸漸上升;薄膜之T/sub m/漸漸下降;XRD繞射峰逐漸減弱,顯示其結晶度有下降的趨勢。在沈澱槽影響方面,70%DMSO沈澱槽製備之薄膜有較好之結晶度,也可由SEM、DSC、XRD等測試中證實。
    In this research, PVDF/PMMA composite membranes were prepared by the isothermal immersion precipitation method. DMSO and water were used as the solvent and nonsolvent, respectively. A wide variety of membrane morphologies were obtained by changing the bath conditions and/or the ratio of the two polymers. SEM, DSC, XRD, and tensile strength tester were used to study the morphologies and physical properties of the membranes. As the composition of PMMA increased, the morphology of the membrane underwent profound changes from more particulate to more cellular form. The tensile strength also gradually increased in this case. That the T/sub m/, H/sub m/, and XRD diffraction peaks decreased with increasing PMMA content suggested that the crystallization capability of PVDF was lowered by blending with PMMA. As to the effects of the precipitation bath, it was found that precipitation in baths containing high concentrations of DMSO tended to yield membranes with high crystallinity, which was confirmed by SEM, DSC, and XRD analysis.
    關聯: 2005高分子聯合會議---第28屆高分子研討會94年國科會高分子學門研究成果發表會94高分子學會年會論文集,4頁
    顯示於類別:[化學工程與材料工程學系暨研究所] 會議論文

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