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    題名: A new UV-curable PU resin obtained through a nonisocyanate process and used as a hydrophilic textile treatment
    作者: Hwang, Jing-Zhong;Wang, Shih-Chieh;Chen, Po-Chen;Huang, Chi-Yuan;Yeh, Jen-Taut;Chen, Kan-Nan
    貢獻者: 淡江大學化學學系
    關鍵詞: Nonisocyanate process;Cyclic carbonate;Hydrophilic;PU;UV curing
    日期: 2012-07
    上傳時間: 2013-03-12 23:16:04 (UTC+8)
    出版者: Dordrecht: Springer Netherlands
    摘要: A new UV-curable hydrophilic PU resin was obtained through a green, nonisocyanate, three-reaction process: (1) a bis(cyclic carbonate) (BCC) compound is prepared by inserting carbon dioxide into an epoxy resin (DGEBA) at atmospheric pressure; (2) an amino-terminated hydrophilic PU (NH2-PU) oligomer is obtained through the ring-opening polymerization of BCC utilizing a difunctional amino hydrophilic (polyether) compound such as Jeffamine D-2000; (3) the UV-curable acrylate-PU (UV-PU) prepolymer is obtained as an adduct from the Michael addition of NH2-PU to a diacrylate-terminated compound, 3-acryloyloxy-2-hydroxypropyl methacrylate (AHM). A polyester (PET) textile was treated with this hydrophilic UV-PU prepolymer and then cured by irradiation with UV light. The UV-PU resin was found to crosslink and anchor to the textile fibers after UV irradiation, resulting in a long-lasting hydrophilic surface for the treated textile. The performance properties of the new PU resin on the treated textile were investigated.
    關聯: Journal of Polymer Research 19(8), 9900(10pages)
    DOI: 10.1007/s10965-012-9900-y
    顯示於類別:[化學學系暨研究所] 期刊論文


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