Synthesis of cis-2,6-tetrahydropyran-4-one via diastereoselectively intramolecular cyclization of β-hydroxy allyl ketone

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/79751

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题名:	Synthesis of cis-2,6-tetrahydropyran-4-one via diastereoselectively intramolecular cyclization of β-hydroxy allyl ketone
作者:	Lee, Adam Shih-Yuan;Lin, Li-Shin;Chang, Yu-Ting
贡献者:	淡江大學化學學系
日期:	2012-05
上传时间:	2013-01-10 13:56:54 (UTC+8)
出版者:	Kidlington: Pergamon
摘要:	A series of cis-2,6-tetrahydropyran-4-ones was synthesized from the intramolecular cyclization reaction of b-hydroxy allyl ketones in the presence of Me3SiOTf as catalyst. The b-hydroxy allyl ketone was prepared from allylation reaction with b-hydroxynitrile without protection of hydroxy functionality under the Barbier-type reaction condition.
關聯:	Tetrahedron 68(20), pp.3915–3919
DOI:	10.1016/j.tet.2012.02.076
显示于类别:	[化學學系暨研究所] 期刊論文

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