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    题名: Synthesis of cis-2,6-tetrahydropyran-4-one via diastereoselectively intramolecular cyclization of β-hydroxy allyl ketone
    作者: Lee, Adam Shih-Yuan;Lin, Li-Shin;Chang, Yu-Ting
    贡献者: 淡江大學化學學系
    日期: 2012-05
    上传时间: 2013-01-10 13:56:54 (UTC+8)
    出版者: Kidlington: Pergamon
    摘要: A series of cis-2,6-tetrahydropyran-4-ones was synthesized from the intramolecular cyclization reaction of b-hydroxy allyl ketones in the presence of Me3SiOTf as catalyst. The b-hydroxy allyl ketone was prepared from allylation reaction with b-hydroxynitrile without protection of hydroxy functionality under the Barbier-type reaction condition.
    關聯: Tetrahedron 68(20), pp.3915–3919
    DOI: 10.1016/j.tet.2012.02.076
    显示于类别:[化學學系暨研究所] 期刊論文

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