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    Title: Preparation of microporous poly(VDF-co-HFP) membranes by template-leaching method
    Authors: Chang, Hsu-Hsien;Yao, Liang-Chin;Lin, Dar-Jong;Cheng, Liao-Ping
    Contributors: 淡江大學化學工程與材料工程學系
    Keywords: Poly(vinylidene fluoride);Porous membrane;Copolymer;Polymer blend
    Date: 2010-04
    Issue Date: 2012-06-14 09:03:33 (UTC+8)
    Publisher: Kidlington: Pergamon
    Abstract: The copolymer of vinylidene fluoride and hexafluoro propylene, poly(VDF–HFP), and the terpolymer of vinylidene fluoride, tetrafluoro ethylene, and hexafluoro propylene, poly(VDF–TEF–HFP), were solution blended at first to form dense composite films. Then, 90% acetone aqueous solution was used to leach out the terpolymer in the film at 5 °C. By varying the fraction of terpolymer in the blend and the leaching condition, microporousmembranes with different porous morphology were produced, as revealed by SEM imaging. When the terpolymer content in the blend was lower than 30 wt%, low porosity (e.g., 24%) asymmetric membranes were obtained. On the other hand, when the terpolymer content approached 50%, skinless membranes with uniform pore distribution (pore size, ca. 1 μm) were produced. These skinless membranes demonstrate high tensile strengths (∼6 MPa) and water fluxes (3000–8000 LMH) that are potentially applicable to micro-filtration operations. Furthermore, crystallinities of the membranes were determined both by X-ray diffractometry and differential scanning calorimetry. Both methods indicated crystallinity near 24%, typical of poly(VDF–HFP) polymer in different forms.
    Relation: Separation and Purification Technology 72(2), pp. 156-166
    DOI: 10.1016/j.seppur.2010.02.001
    Appears in Collections:[化學工程與材料工程學系暨研究所] 期刊論文

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