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    題名: FeCl3 Catalyzed Barbier Homocoupling Reaction for Synthesis of Symmetric Biaryls
    作者: Lee, Adam Shih-Yuan;Chen, Pin-Lung;Chang, Yu-Ting;Tsai, Heng-Tser
    貢獻者: 淡江大學化學學系
    關鍵詞: Biaryl;Barbier homocoupling reaction;Iron salt
    日期: 2012-03-01
    上傳時間: 2012-05-23 10:18:49 (UTC+8)
    摘要: A series of biaryls and biheteroaryls were synthesized by the Barbier reaction of aryl bromide with magnesium powder and 1,2-dibromoethane in the presence of FeCl3 in THF under reflux reaction condition. The catalytic system differentiates itself from other homocoupling reactions catalyzed by iron salts in that it requires neither the preliminary preparation of Grignard reagent nor the addition of an oxidant.
    關聯: Journal of the Chinese Chemical Society 59(3), pp.452–454
    DOI: 10.1002/jccs.201100679
    顯示於類別:[化學學系暨研究所] 期刊論文

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