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    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/76957

    Title: FeCl3 Catalyzed Barbier Homocoupling Reaction for Synthesis of Symmetric Biaryls
    Authors: Lee, Adam Shih-Yuan;Chen, Pin-Lung;Chang, Yu-Ting;Tsai, Heng-Tser
    Contributors: 淡江大學化學學系
    Keywords: Biaryl;Barbier homocoupling reaction;Iron salt
    Date: 2012-03-01
    Issue Date: 2012-05-23 10:18:49 (UTC+8)
    Abstract: A series of biaryls and biheteroaryls were synthesized by the Barbier reaction of aryl bromide with magnesium powder and 1,2-dibromoethane in the presence of FeCl3 in THF under reflux reaction condition. The catalytic system differentiates itself from other homocoupling reactions catalyzed by iron salts in that it requires neither the preliminary preparation of Grignard reagent nor the addition of an oxidant.
    Relation: Journal of the Chinese Chemical Society 59(3), pp.452–454
    DOI: 10.1002/jccs.201100679
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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