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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/6907


    Title: 聚偏二氟乙烯接枝共聚合體自組裝特性與奈米孔隙結構之研究
    Other Titles: Study of PVDF Graft Copolymer Self-Assembly Feature and Nanopore Structure Morphology
    Authors: 林達鎔
    Contributors: 淡江大學化學工程與材料工程學系
    Keywords: 原子轉移自由基聚合;聚偏二氟乙烯;接枝共聚合體;自組裝;奈米孔隙;多孔性薄膜
    Date: 2006
    Issue Date: 2009-03-16 15:22:41 (UTC+8)
    Abstract: 聚偏二氟乙烯(PVDF)為一穩定性極佳之線性高分子,並廣泛的應用於工程材料及生 醫材料。在本研究,我們利用原子轉移自由基聚合法(ATRP),合成接枝共聚合體(graft copolymer)。與自組裝特性(self-assembly)的區段共聚合體(block copolymer)相類似,接 枝共聚合體也同樣具有此種自組裝行為。研究工作的重點在於:高分子分子量,接枝比 例,溶劑與溫度等因素,對於的自組裝特性的影響,並深入分析探討對於自組裝形態結 構的調控。短期目標是以接枝共聚合體與聚甲基丙烯酸甲酯(PMMA)摻合,製備奈米 孔隙結構在20奈米左右的多孔薄膜,利用其自組裝能力,達到均勻的奈米結構形態。
    Appears in Collections:[化學工程與材料工程學系暨研究所] 研究報告

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