English  |  正體中文  |  简体中文  |  全文筆數/總筆數 : 58210/91779 (63%)
造訪人次 : 13776024      線上人數 : 56
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
搜尋範圍 查詢小技巧:
  • 您可在西文檢索詞彙前後加上"雙引號",以獲取較精準的檢索結果
  • 若欲以作者姓名搜尋,建議至進階搜尋限定作者欄位,可獲得較完整資料
  • 進階搜尋
    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/67862

    題名: Oxidative Decomposition of Reactive Blue C.I. 19 with Sodium Hypochlorite
    作者: Ho, Chih-Hsuan;Chen, Luke;Ho, Yen-Peng;Yang, Chen-Lu
    貢獻者: 淡江大學水資源及環境工程學系
    關鍵詞: Reactive Blue 19;anthraquinone dyes;decomposition;reaction kinetics;decolorization;COD reduction
    日期: 2010-01
    上傳時間: 2011-10-23 02:08:57 (UTC+8)
    出版者: New Rochelle: Mary Ann Liebert, Inc. Publishers
    摘要: AbstractReaction kinetics of Reactive Blue C.I. 19 (RB 19) dye and sodium hypochlorite (NaOCl) were investigated. Decline of RB 19 was monitored continuously by an ultraviolet (UV)-Vis spectrophotometer to avoid sampling errors. The purpose of this study is to develop a kinetic model for reactor and process design to establish hypochlorite oxidation as a viable alternative to advanced oxidation processes for textile effluent decolorization. Results were in agreement with 0.5-order reaction kinetics with respect to the RB 19 concentration. The lumped rate constant of the pseudo-0.5-order reaction is proportional to the NaOCl concentration. The Arrhenius activation energy obtained from the slope of the best-fit line is 76.6?kJ/mol, with a corresponding preexponential factor of 1.388?×?1010. The reaction rate is strongly affected by the pH of the solution. During the oxidation decomposition process, color was rapidly removed by the NaOCl but chemical oxygen demand (COD) resisted the treatment. A molar ratio of more than 44 is essential for OCl-to completely decompose the dye molecules thus removing COD from the solution. A system of liquid chromatography mass spectrometry (LC/MS) was used to determine the intermediates in the initial steps of the decomposition process.
    關聯: Environmental Engineering Science 27(1), pp.103-109
    DOI: 10.1089/ees.2009.0285
    顯示於類別:[水資源及環境工程學系暨研究所] 期刊論文


    檔案 大小格式瀏覽次數



    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - 回饋