使矽烷脫矽之有效且高度化學選擇性之方法

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/61813

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題名:	使矽烷脫矽之有效且高度化學選擇性之方法
其他題名:	An Efficient and Highly Chemoselective Method to Desilylate Silyl Ethers
作者:	葉明國
貢獻者:	淡江大學化學學系
關鍵詞:	Sonochemistry;Ultrasound;Cavitation;Desilylation;Chemoselection;Deprotection
日期:	1995-12
上傳時間:	2011-10-15 23:44:11 (UTC+8)
摘要:	An efficient and highly chemoselective desilylating method is described. Trimethylsilyl ethers (0.25 M) in a CH3OH/CCl4 (1:1) solvent mixture are deprotected to their corresponding alcohols with ultrasound in a commercial ultrasonic cleaning bath. Selective deprotection of tert-butyldimethylsilyl ethers of benzyl alcohols and phenols is achieved under ultrasonic conditions. We deprotected also tert-butyldimethylsilyl ethers of primary alcohols, whereas tert-butyldimethylsilyl ethers of secondary and tertiary alcohols are stable under these conditions.
關聯:	中國化學會會誌 42(6)，頁912-922
DOI:	10.1002/jccs.199500126
顯示於類別:	[化學學系暨研究所] 期刊論文

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