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    Title: Structure and magnetic property of μ-alkoxo–μ-6-methoxypurinate double bridged dinuclear copper(II) complex
    Authors: Lai, Tung-Ching;Chen, Wen-hao;Lee, Chin-jhan;Wang, Bo-cheng;Wei, Ho-hsiang
    Contributors: 淡江大學化學學系
    Keywords: Copper(II) complexes;Dinuclear copper(II) complexes;Purine metal complexs;Alkoxo–purinato bridges;Crystal structures;Magnetic properties
    Date: 2009-10-29
    Issue Date: 2011-10-15 23:37:41 (UTC+8)
    Publisher: Amsterdam: Elsevier BV
    Abstract: A new μ-alkoxo–μ-6-methoxypurinate double bridged dinuclear copper(II) complex [Cu2(L)(μ-6-meo-pur)(dmf)] (1) (μ-6-meo-pur = μ-6-methoxypurinate, H3L = 1,3-bis(3,5-tert-butyl-salicylideneamino)-2-propanol; dmf = N,N-dimethylformamide) has been prepared and structurally characterized. The single crystal X-ray analysis show that the structure of complexes 1 is dimeric with two adjacent copper(II) atoms double bridged by μ-alkoxo–μ-purinato with the Cu···Cu distances and Cu–O(alkoxo)–Cu angles 3.227(3) Å and 110.30(11)°, respectively. Magnetic measurements reveal that 1 is a ferromagnetically coupled with exchange parameter of 2J = 56.2 cm−1. DFT calculation of spin density of HOMO for 1 was presented.
    Relation: Journal of Molecular Structure 935(1-3), pp.97-101
    DOI: 10.1016/j.molstruc.2009.06.041
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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