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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61751

    Title: Synthesis of cis-3,4-diaryl α-methylene-γ-butyrolactams via sonochemical Barbier-type reaction
    Authors: Lee, Adam Shih-yuan;Chang, Yu-ting
    Contributors: 淡江大學化學學系
    Date: 2010-05
    Issue Date: 2011-10-15 23:36:50 (UTC+8)
    Publisher: Kidlington: Pergamon
    Abstract: A series of cis-3,4-diaryl α-methylene-γ-butyrolactams were synthesized by the addition reaction of 3-phenylallyl bromide with N-tosyl aldimine via sonochemical Barbier-type reaction condition and then followed by the in situ intramolecular amidation. The cis-3,4-diaryl α-methylene-γ-butyrolactam was obtained as the sole regio- and stereoisomeric product when N-tosyl aldimine was used as the substrate whereas the monoaryl α-methylene-γ-butyrolactam was also generated when N-phenyl aldimine was used.
    Relation: Tetrahedron Letters 51(29), pp.3800-3802
    DOI: 10.1016/j.tetlet.2010.05.057
    Appears in Collections:[Graduate Institute & Department of Chemistry] Journal Article

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