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    题名: Preparation and characterization of Nd2Zr2O7 nanocrystals by a polymeric citrate precursor method
    作者: Lee, Y. H.;Sheu, H. S.;Kao, H.C. I.
    贡献者: 淡江大學化學學系
    关键词: Phase transitions;Rietveld analysis;Powder diffraction;Oxides
    日期: 2010-09
    上传时间: 2011-10-15 23:28:28 (UTC+8)
    出版者: Lausanne: Elsevier S.A.
    摘要: Nd2Zr2O7 was prepared by a polymeric citrate precursor method and then calcined at 700–1400 °C in static air. Larger nano-size particles were obtained with increasing calcination temperature. Samples have a defect fluorite phase if they are prepared below 1000 °C. However, if it is heat treated at temperature between 1100 and 1400 °C, a disordered pyrochlore phase is obtained. Unit cell a-axis dimension of the samples gradually increases with increasing preparation temperature. The amount of cation antisite and the occupancy factor of the O(3) site in the pyrochlore phase gradually decrease in the samples prepared at higher temperatures. In other words, the ordering process is an activated behavior. Activation energies of the cation and anion ordering are 0.12(1) and 0.23(2) eV, respectively, equivalent to 12(1) and 22(2) kJ mol−1.
    關聯: Materials Chemistry and Physics 124(1), pp.145-149
    DOI: 10.1016/j.matchemphys.2010.06.006
    显示于类别:[化學學系暨研究所] 期刊論文

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