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    題名: New Copper(I) Complex with Triazole Derivative Ligand Containing α-Diimine Moiety: Synthesis, Structure, Luminescence and Electrochemistry
    作者: 王文竹;Wang, Wen-jwu;林建合;Lin, Chien-ho
    貢獻者: 淡江大學化學學系
    關鍵詞: α-Diimine ligands;Luminescence;Triazole
    日期: 2006-12-01
    上傳時間: 2013-07-29 15:36:57 (UTC+8)
    出版者: 臺北市:中國化學學會
    摘要: One cuprous complex [Cu(L)(PPh3)I] was obtained by reaction of [Cu(PPh3)3I] (PPh3 = triphenylphosphine) with a new a-diimine ligand L (N-diphenylmethylene-3,5-di(2'-pyridyl)-4-amino-1,2,4-triazole). The complex has been characterized by UV-Vis, luminescence, 1H NMR spectroscopy and cyclic voltammetric study. The structure of ligand L and complex are confirmed by single crystal X-ray diffraction study. The compound [Cu(L)(PPh3)I] crystallizes in the monoclinic P21/c space group with a = 19.9291(4), b = 10.0691(2), c = 21.9245(5), α = γ = 90, β = 92.481(10), and Z = 4. The complex shows a MLCT band in the 350~545 nm region and exhibits luminescent emission at 600 nm at room temperature in dichloromethane solution. Cyclic voltammogram of [Cu(L)(PPh3)I] shows a quasi-reversible redox couple of the copper center at 0.67 V for Cu(I)/Cu(II) and an irreversible reduction potential at -0.98 V accompanied by a stripping peak of copper at -0.11 V for Cu(I)/Cu(0).
    關聯: Journal of the Chinese Chemical Society=中國化學會會誌 53(6), pp.1309-1316
    DOI: 10.1002/jccs.200600175
    顯示於類別:[化學學系暨研究所] 期刊論文

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