Magnetic properties of M/sub 3/ [ Fe(CN)/sub 6/ ] /sub 2/ .bcdot.XH/sub 2/O (M=Co(II), Ni(II), Cu(II), Zn(II))

機構典藏 > College of Sciences > Graduate Institute & Department of Chemistry > Journal Article > Item 987654321/61645

Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/61645

Title:	Magnetic properties of M/sub 3/ [ Fe(CN)/sub 6/ ] /sub 2/ .bcdot.XH/sub 2/O (M=Co(II), Ni(II), Cu(II), Zn(II))
Authors:	徐惠麗;Shyu, H. L.;林施娜;Lin, S. N.;魏和祥;Wei, Ho-hsiang
Contributors:	淡江大學化學學系
Keywords:	Molecular magnet;Mossbauer effect;Magnetic hystersis;Cyanoferrates
Date:	1995-10
Issue Date:	2011-10-15 23:24:53 (UTC+8)
Abstract:	Compounds of the type M3[Fe(CN)6]2XH2O (M = Co(II), Ni(II), Cu(II), and Zn(II)) were prepared and magnetic properties of their powders were investigated by means of EPR spectra, Mössbauer effect and magnetic susceptibility measurements. The temperature dependence of the magnetization for the complexes Co3[Fe(CN)5]2- 10H2O, Ni3[Fe(CN)6]2-10H2O and Cu3[Fe(CN)6]2-4H2O revealed that below the critical temperatures 15, 22 and 20 K respectively, these complexes have zero-field magnetization. The magnetic hysteresis at 10 K for Co(II), Ni(II) and Cu(II) complexes was observed. Mössbauer spectra at 4.2 K for the compounds are discussed.
Relation:	Journal of the chinese chemical society 42(5),　p.791-795
DOI:	10.1002/jccs.199500106
Appears in Collections:	[Graduate Institute & Department of Chemistry] Journal Article

Files in This Item:

File	Size	Format
index.html	0Kb	HTML	104	View/Open