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    請使用永久網址來引用或連結此文件: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/61579

    題名: Efficient syntheses of (−)-shikimate and (−)-quinate 3-phosphate via trans vicinal diol protection with 2,2,3,3-tetramethoxybutane (TMB) of shikimic and quinic acids
    作者: Shih, Tzenge-lien;Wu, S. H.
    貢獻者: 淡江大學化學學系
    關鍵詞: shikimic acid;quinic acid;shikimate 3-phosphate;quinate 3-phosphate;2,2,3,3-tetramethoxybutane
    日期: 2000-04
    上傳時間: 2011-10-15 23:18:37 (UTC+8)
    摘要: (−)-Shikimate 3-phosphate and (−)-quinate 3-phosphate can be synthesized by selective protection of their trans diol functionality using 2,2,3,3-tetramethoxybutane (TMB) using d-(−)-shikimic acid and d-(−)-quinic acid as starting materials. This versatile reagent facilitates the synthesis of these important biological targets in fewer steps than previously reported. By the proper choice of protecting group for C-3 hydroxyl in d-(−)-quinic acid, it can be converted to a key intermediate in the synthesis of (−)-shikimate 3-phosphate.
    關聯: Tetrahedron letters41, pp.2957-2959
    DOI: 10.1016/S0040-4039(00)00280-X
    顯示於類別:[化學學系暨研究所] 期刊論文





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