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    題名: Effects of collisional cooling on ion detection in a quadrupole ion trap mass spectrometer
    作者: Wu, H. F.;吳慧芬;Brodbelt, J. S.
    貢獻者: 淡江大學化學學系
    關鍵詞: collisional cooling;collision-activated dissociation;ion detection
    日期: 1912-01
    上傳時間: 2011-10-15 23:18:21 (UTC+8)
    摘要: The effects of collisional cooling on the storage and detection of ions in a quadrupole ion trap mass spectrometer are examined. Four parameters that affect the storage of ions are evaluated: the pressure of the buffer gas: the qz value which establishes the ion trapping environment; the cooling time during which ions may collapse to the center of the trap; and the supplementary a.c. voltage used to kinetically excite selected ions. The ion trap may be operated effectively at a low helium pressure (0.1 mTorr) if a sufficient delay period is added to allow the diffuse ion cloud to collapse to the center of the trap prior to detection. For a typical experiment, this modified operation at low pressures involves allowing the ions to undergo approximately 30–100 collisions (i.e. in a ≈30 ms interval at 0.1 mTorr). At low helium pressures (≈0.1 mTorr), more ions may be trapped at higher qz values. Collision-activated dissociation (CAD) at low helium pressures indicates that the average internal energy deposition is higher, and sensitivity is not lost, if a collisional cooling delay is added. This latter result potentially has great analytical relevance for CAD of biomolecules which require greater internal energy deposition to induce fragmentation.
    關聯: International Journal of Mass Spectrometry and Ion Processes 115(1), pp.67-81
    DOI: 10.1016/0168-1176(92)85032-U
    顯示於類別:[化學學系暨研究所] 期刊論文

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