Correlation between polarographic halfwave potential and electronic spectra of cis-trans compleses of chromium(III) and rhodium(III)

淡江大學機構典藏 > 理學院 > 化學學系暨研究所 > 期刊論文 > Item 987654321/61546

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题名:	Correlation between polarographic halfwave potential and electronic spectra of cis-trans compleses of chromium(III) and rhodium(III)
作者:	Wei, Ho-hsiang
贡献者:	淡江大學化學學系
日期:	1977-12
上传时间:	2011-10-15 23:15:31 (UTC+8)
摘要:	A linear correlation between half-wave potential (E1/2) for the process M(III)→M(II) and the first d-d transition band (v) of the types cis and trans-[M(en)2X2]n+ (M=Cr(III) and Rh(III), X=ONO−, NCS−, F−, Cl−, Br−, I−, H2O, DMF, DMSO, n=1, 3) was found. The plots of the difference in half-wave potential (ΔE1/2) against the difference in the first d-d transition hand (Δv) for the cis and trans isomer are straight lines. The equations, E1/2=β/nαF+K1 and ΔE1/2=(β/NαF)Δ were derived, and used to describe the linear correlations between polarographic behavior and electronic spectrum.
關聯:	Journal of the Chinese chemical society24(4),　p.147-156
DOI:	10.1002/jccs.197700025
显示于类别:	[化學學系暨研究所] 期刊論文

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