淡江大學機構典藏:Item 987654321/61523
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    题名: cis- anti- cis-Dicyclohexyl-18-crown-6–thiacetazone–methanol (1/2/2)
    作者: Fonari, M. S.;Ganin, E. V.;Simonov, Y. A.;Wang, W.-J.
    贡献者: 淡江大學化學學系
    日期: 2006-03
    上传时间: 2013-05-30 15:19:55 (UTC+8)
    出版者: Malden: Wiley-Blackwell Publishing, Inc.
    摘要: In the title compound [systematic name: 2,5,8,15,18,21-tricyclo[20.4.0.09,14]hexacosane-4-acetylaminobenzaldehyde thiosemicarbazone-methanol (1/2/2)], C20H36O6·2C10H12N4OS·2CH3OH, the cis-anti-cis-dicyclohexyl-18-crown-6 molecule resides on an inversion center, and two thiacetazone molecules are linked to the macrocycle via N-HO hydrogen bonds of the terminal amino group [NO = 3.017 (2) and 3.092 (2) Å]. These units are further associated into chains via bridging methanol molecules acting both as an H-atom donor [via an O-HS contact, with OS = 3.182 (3) Å] and as an H-atom acceptor [via an N-HO contact, with NO = 2.848 (3) Å].
    關聯: Acta Crystallographica, Section E 62(3), pp.O911-O913
    DOI: 10.1107/S1600536806003709
    显示于类别:[化學學系暨研究所] 期刊論文

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