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Please use this identifier to cite or link to this item:
https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/61523
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Title: | cis- anti- cis-Dicyclohexyl-18-crown-6–thiacetazone–methanol (1/2/2) |
Authors: | Fonari, M. S.;Ganin, E. V.;Simonov, Y. A.;Wang, W.-J. |
Contributors: | 淡江大學化學學系 |
Date: | 2006-03 |
Issue Date: | 2013-05-30 15:19:55 (UTC+8) |
Publisher: | Malden: Wiley-Blackwell Publishing, Inc. |
Abstract: | In the title compound [systematic name: 2,5,8,15,18,21-tricyclo[20.4.0.09,14]hexacosane-4-acetylaminobenzaldehyde thiosemicarbazone-methanol (1/2/2)], C20H36O6·2C10H12N4OS·2CH3OH, the cis-anti-cis-dicyclohexyl-18-crown-6 molecule resides on an inversion center, and two thiacetazone molecules are linked to the macrocycle via N-HO hydrogen bonds of the terminal amino group [NO = 3.017 (2) and 3.092 (2) Å]. These units are further associated into chains via bridging methanol molecules acting both as an H-atom donor [via an O-HS contact, with OS = 3.182 (3) Å] and as an H-atom acceptor [via an N-HO contact, with NO = 2.848 (3) Å]. |
Relation: | Acta Crystallographica, Section E 62(3), pp.O911-O913 |
DOI: | 10.1107/S1600536806003709 |
Appears in Collections: | [化學學系暨研究所] 期刊論文
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