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    Title: Kinetic study of Bi1.8Pb0.4Ca2Sr2Cu3Oy superconductor in water
    Authors: Wang, C. M.;Wei, T.P.;Kao, H.-C. I.
    Contributors: 淡江大學化學學系
    Date: 1993-10
    Issue Date: 2013-07-09 15:29:56 (UTC+8)
    Publisher: Amsterdam: Elsevier BV * North-Holland
    Abstract: The reaction of Bi1.8Pb0.4Ca2Sr2Cu3Oy powder in water was studied quantitatively. It was found that the [H3O+] ion would act as a catalyst in this reaction and the initial rate equation was R0 = -d[A]0/dt = k[A]0[H3O+]0.20, where [A] represented the surface area of the superconducting powder. The rate constant, k, obtained at 10, 25 and 40°C was 3.98, 8.8 and 19.6 × 10-4 mol min-1 cm-2 M0.8, respectively. The activation energy and pre-exponential factor calculated from the Arrhenius equation were respectively 39.1 kJ mol-1 and 6.4 × 103 mol min-1 cm-2 M0.8.
    Relation: Physica C: Superconductivity 215(3-4), pp.391-394
    DOI: 10.1016/0921-4534(93)90240-Q
    Appears in Collections:[化學學系暨研究所] 期刊論文

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