English  |  正體中文  |  简体中文  |  Items with full text/Total items : 60861/93527 (65%)
Visitors : 1506074      Online Users : 13
RC Version 7.0 © Powered By DSPACE, MIT. Enhanced by NTU Library & TKU Library IR team.
Scope Tips:
  • please add "double quotation mark" for query phrases to get precise results
  • please goto advance search for comprehansive author search
  • Adv. Search
    HomeLoginUploadHelpAboutAdminister Goto mobile version
    Please use this identifier to cite or link to this item: https://tkuir.lib.tku.edu.tw/dspace/handle/987654321/60222

    Title: 溫度敏感型之幾丁聚醣水膠製備與性質研究
    Authors: 董崇民;邱作沛
    Contributors: 淡江大學化學工程與材料工程學系;淡江大學水資源及環境工程學系
    Keywords: 幾丁聚醣;溫度敏感性;聚氮-異丙基丙烯醯胺;甲基丙烯酸聚乙二醇酯;Chitosan;Thermal-responsive;PNIPAAm;PEGMA;LCST
    Date: 2009-01
    Issue Date: 2011-10-13 13:29:40 (UTC+8)
    Publisher: 臺北市:大同大學
    Abstract: 本研究利用無乳化劑乳化聚合來製備生物相容性佳且具備溫度敏感性質的的幾丁聚醣乳膠共聚物,一方面利用幾丁聚醣增加生物相容性,另一方面導入親水性單體PEGMA來提昇乳膠共聚物的LCST值。CS與NIPAAm共聚合的結果,其LCST值都約在32~33 degree C附近,與純PNIPAAm的LCST相差無幾,因此推測CS對LCST值的影響不大。CS、NIPAAm和PEGMA的乳膠共聚物,其LCST值大部分隨PEGMA的含量增加有提昇的效果,但因為單體反應性的不同,分別得到PNIPAAm-rich與PEGMA-rich的鏈段,而呈現兩段階段LCST。另外,觀察在不同反應時間取樣所得到產物的LCST值變化,發現除了10分鐘為一階段LCST之外,其餘皆為兩階段,而且隨反應時間增長,LCST值逐漸往低溫移動。
    In this study, chitosan (CS) latex copolymer with excellent bi degree Compatible and thermal-responsive properties was synthesized with NIPAAm and PEGMA in an emulsifier-free emulsion polymerization. The LCST value of CS-PNIPAAm copolymer was 32-33 degree C almost the same as PNIPAAm. It implied that the CS did not influence the LCST value. Moreover, the LCST value of CS-PNIPAAm-PEGMA copolymer was increased with increasing the amount of hydrophilic PEGMA. However, two stages of transition behavior were observed because PNIPAAm-rich and PEGMA-rich chains were obtained due to the difference in monomer reactivity between NIPAAm and PEGMA. Therefore, different CS-PNIPAAm-PEGMA copolymers obtained at different reaction times would have different LCST values. As reaction pr degree Ceeded, the LCST shifted to lower temperature and two-transitions became obvious.
    Relation: 2009中華民國高分子學會年會暨軟性電子國際研討會&國科會高分子學門成果發表會論文集=Proceedings of 2009 Annual Meeting of the Polymer Society,4頁
    Appears in Collections:[Graduate Institute & Department of Water Resources and Environmental Engineering] Proceeding
    [Graduate Institute & Department of Chemical and Materials Engineering] Proceeding

    Files in This Item:

    There are no files associated with this item.

    All items in 機構典藏 are protected by copyright, with all rights reserved.

    DSpace Software Copyright © 2002-2004  MIT &  Hewlett-Packard  /   Enhanced by   NTU Library & TKU Library IR teams. Copyright ©   - Feedback