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    Please use this identifier to cite or link to this item: http://tkuir.lib.tku.edu.tw:8080/dspace/handle/987654321/5610

    Title: 多核異金屬錯合物之旋狀態及磁性之研究(III)
    Other Titles: Spin States and Magnetic Properties & Multiheternuclear Metallic Complexes(III)
    Authors: 魏和祥
    Contributors: 淡江大學化學學系
    Keywords: 鐵錯合物;磁性;梅氏效應;Iron complex;Magnetic property;Mossbauer effect
    Date: 1995
    Issue Date: 2009-03-16 12:43:50 (UTC+8)
    Abstract: 本計畫擬進行下列兩方面的研究:(1)設計具 有鐵磁性之錯合物:a.雙核或多核金屬錯合物, M(II)-Fe(III)(低自旋),M(II)-Cu(II)M(II)=Zn(II),Cu(II), Ni(II),Co(II),VO(II),Mn(II)等;b.有機自由基分子-無 機錯合物;(2)設計類似生物活性Fe(III)-Cu(II)或 M(II)-Cu(II)多核錯合物,合成下列錯合物:a.合成 XFe-Porphyrin或XFe-Phthalocyanine,X為軸上取代基=Cl /sup -/,OH/sup -/,NCS,Im,C10/sub4//sup -/,OR,Py or CH/sub 3 /-or CH/sub 3/-取代Im及Py;b.設計單核銅[ CuL/sub 2/] 或雙核銅[ CuL/sub 2/] /sub 2/錯合物之合物;c.組合 雙核鐵銅錯核物XFe-Porphyrin.CuL/sub 2/,及三核鐵 銅錯合物XFe-Porphyrin.CuL/sub 2/.Porphyrin.Fe.X;d.合成 M(II)L/sub 1/-Cu(II)L/sub 2/錯合物,M(II)=Co(II),Ni(II), Zn(II),Cu(II),VO(II);L/sub 1/為環配位基,L/sub 2/為 Schiff-Base配位基.利用SQUID及Mossbauer測定上述各 系列錯合物之自旋狀態及磁性,並進一步討論 Fe(III)-porphyrin之配位子效應.
    Appears in Collections:[Graduate Institute & Department of Chemistry] Research Paper

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